If you can ping this host over the LAN/WAN, his MAC address will be cached in ARP table of your NIC for a while, so, from command prompt:
ping 1.2.3.4
after some echo replies from host 1.2.3.4
arp -a
and you will see MAC address of 1.2.3.4
You can try to specific as
/sbin/arp -a 192.168.1.1
You can also Try : PSTOOLS (freeware from Sysinternals) PSEXEC
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